| # | Crew | Time |
|---|---|---|
| 1 | NEDNetherlandsRoos De Jong, Benthe Boonstra | 6:49.34 |
| 2 | CHNChinaYunxia Chen, Ling Zhang | 6:50.22 |
| 3 | AINIndividual Neutral AthletesTatsiana Klimovich, Alena Furman | 6:53.26 |
| 4 | SUISwitzerlandSalome Ulrich, Fabienne Schweizer | 6:55.35 |
| 5 | FRAFranceElodie Ravera Scaramozzino, Emma Lunatti | 6:57.39 |
| 6 | GREGreeceEvangelia Anastasiadou, Zoi Fitsiou | 7:04.10 |
Times in Sydney time (AEDT). Data: World Rowing