| # | Crew | Time |
|---|---|---|
| 1 | GERGermanyValentin Luz, Kathrin Marchand | 6:58.64 |
| 2 | UKRUkraineStanislav Samoliuk, Dariia Kotyk | 7:05.33 |
| 3 | AUSAustraliaLisa Greissl, Sam Stunell | 7:06.60 |
| 4 | GBRGreat BritainSamuel Murray, Annabel Caddick | 7:09.41 |
| 5 | AINIndividual Neutral AthletesAnna Piskunova, Anton Voronov | 7:12.26 |
| 6 | FRAFranceEva David, Laurent Cadot | 7:17.23 |
Times in Sydney time (AEDT). Data: World Rowing