| # | Rider | Time |
|---|---|---|
| 1 | SLOPrimož RogličRed Bull–Bora–Hansgrohe | |
| 2 | LUXMats WenzelEquipo Kern Pharma | |
| 3 | FRABruno ArmirailGroupama–FDJ | |
| 4 | ESPJuan AyusoUAE Team Emirates XRG | |
| 5 | NEDAlex MolenaarCaja Rural–Seguros RGA | |
| 6 | POLDanny van der TuukEuskaltel–Euskadi | |
| 7 | ITALorenzo GermaniGroupama–FDJ | |
| 8 | ESPMario AparicioBurgos Burpellet BH | |
| 9 | ESPPablo TorresUAE Team Emirates XRG | |
| 10 | ESPEnric MasMovistar Team |
Times in Sydney time (AEDT). Results: Wikipedia, “2025 Volta a Catalunya”, CC BY-SA 4.0. Unofficial, updated after the event.