| # | Rider | Time |
|---|---|---|
| 1 | SLOPrimož RogličRed Bull–Bora–Hansgrohe | 1h 58' 27" |
| 2 | BELLaurens De PlusINEOS Grenadiers | + 14" |
| 3 | BELLennert Van EetveltLotto | + 14" |
| 4 | FRADorian GodonDecathlon–AG2R La Mondiale | + 19" |
| 5 | BELSylvain MoniquetCofidis | + 19" |
| 6 | ITALorenzo FortunatoXDS Astana Team | + 19" |
| 7 | NZLCorbin StrongIsrael–Premier Tech | + 19" |
| 8 | GBRSimon YatesVisma–Lease a Bike | + 19" |
| 9 | FRAAxel LauranceINEOS Grenadiers | + 19" |
| 10 | FRARudy MolardGroupama–FDJ | + 19" |
Times in Sydney time (AEDT). Results: Wikipedia, “2025 Volta a Catalunya”, CC BY-SA 4.0. Unofficial, updated after the event.